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81.
己二酸是合成尼龙-66和尼龙-46纤维的重要原料,并进一步用于生产许多重要的化工产品。工业上的己二酸多采用以硝酸为氧化剂的两步法合成,该工艺不仅工艺复杂,而且对设备有腐蚀作用,还会释放大量的温室气体N_2O。本文以负载型Pt/SiO_2、Fe/SiO_2和Pt-Fe/SiO_2为催化剂,采用过氧化氢和氧气为氧源,研究了环己烷一步氧化制己二酸的绿色合成路线。对催化剂进行ICP、BET比表面积、XRD、TEM等表征,结果表明,Pt-Fe/SiO_2催化剂中不存在与Pt或Fe对应的衍射峰。在最佳反应条件下,用高压釜进行了催化剂性能评价,结果表明,Pt-Fe/SiO_2催化活性略优于Pt/SiO_2和Fe/SiO_2。在环己烷转化率为28%的情况下,己二酸选择性达到33%。 相似文献
82.
Ahmed Labena Ahmed Hamed Eman H. I. Ismael Samy M. Shaban 《Journal of surfactants and detergents》2020,23(5):991-1004
The Egyptian oil and gas industry is suffering from severe metal corrosion problems, particularly microbial-induced corrosion. There is limited knowledge on the corrosion inhibition of carbon steels in the presence of an acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. Therefore, in this study, novel Gemini cationic surfactants, in three forms depending on variation in alkyl chains of 8, 12, and 16 carbon atoms named FHPAO, FHPAD, and FHPAH, respectively, were synthesized and characterized by Fourier transform infrared and nuclear magnetic resonance spectroscopy. The surface parameters and the thermodynamic of the synthesized surfactants were evaluated at three different temperatures, 20, 40, and 60 °C. The synthesized Gemini cationic surfactants were tested as broad-spectrum antimicrobial, antibacterial and anticandida agents. They evaluated as biocides and corrosion inhibitors against Acidithiobacillus ferrooxidans. FHPAD showed higher adsorption ability at the solution interface and higher affinity to construct micelles than FHPAO and FHPAH. Both adsorption and micellization processes were hydrophobic and temperature dependent. FHPAO, FHPAD and FHPAH exhibited wide-spectrum antimicrobial activities, and the highest activity and the lowest minimum bactericidal/fungicidal inhibitory concentrations were attributed to FHPAD. Furthermore, synthesized FHPAD demonstrated the highest metal corrosion inhibition efficiency of 95.5% at 5 mM in comparison to 87.5% and 81.7% for FHPAO and FHPAH, respectively. In conclusion, this study provides novel synthesized cationic surfactants with many applications in the oil and gas industry, such as broad-spectrum antimicrobial, biocides, and corrosion inhibitors for acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. 相似文献
83.
Caio Machado Fernandes Marcos Vinícius Palmeira de Mello Nazir Escarpini dos Santos Alessandra Mendonça Teles de Souza Mauricio Lanznaster Eduardo Ariel Ponzio 《工业材料与腐蚀》2020,71(2):280-291
4-Chloro-N-(pyridin-2-ylmethyl)aniline (CPYA) was synthesized by a simple and inexpensive method and tested as a corrosion inhibitor in acid medium for mild steel by using gravimetric studies and electrochemical measurements. An average maximum efficiency of 96.0% was achieved at 4.59 mmol/L. Corrosion kinetic and thermodynamic parameters were also analyzed. Surface analyses (atomic force microscopy and scanning electron microscopy) show that protection is enabled by adsorption on the metal, forming a film. Quantum chemical calculations were performed to access information regarding the molecular structure in the corrosive medium and to support interpretation of the results obtained by experimental methods. 相似文献
84.
Dr. Kristina Goncharenko Dr. Michele Mari Dr. Yves P. Auberson Brieuc Matagne 《ChemMedChem》2020,15(24):2359-2362
The European Federation for Medicinal Chemistry (EFMC) created the Young Scientists Network (YSN) to support early-career medicinal chemists and chemical biologists. By doing this, it addressed the rapid changes taking place in the scientific community and in our society, such as the rise of social media, the evolution of the gender balance in the scientific population, and educational needs. Creating the YSN was also a way to ensure that the next generation of scientists would contribute to shaping EFMC's strategy, while recognizing and addressing their needs. The YSN was set up as a very dynamic concept, and has now developed to the point where its impact is evident. The activities it promotes complement EFMC's community support and scientific opportunities, rejuvenating the Federation and preparing it for the future. It also provides opportunities for many brilliant young scientists, who do not hesitate to invest time and energy in supporting our community and shaping their own future. 相似文献
85.
Various statistical approaches such as classical regression and modern machine learning methods have been applied to measurement data for estimating the status of manufacturing processes, which is now boosted by the movement of Internet of Things (IoT). In this study, we attempt to integrate an analytical tool model of surface roughness and measurement data of CNC turning to develop a modeling approach which does not depend too much on data, but also effectively uses existing analytical models. As in previous researches, we use cutting speed, feed rate, depth of cut and three acceleration components from an accelerometer to predict surface roughness. Co-Kriging method is employed to integrate the above measurements and a well-known model of surface roughness in turning. It was confirmed that the approach improved the prediction accuracy when only small amount of data is available for model construction. Meanwhile, the accuracy of ordinary Kriging method, which only depends on data, is suitable when measurement data sufficiently spans the parameter space, being expected that it may be rare in actual operations. We also attempted to detect outlier of measurements using the Co-Kriging method, which might be a non-trivial task when there is no additional information to evaluate the validity of the measurement data. 相似文献
86.
ABSTRACT Aqueous solutions of 4,4′-(1,2-ethanediyldinitrilo)bis-(2-pentanone) (EDDBP) have been used in a novel green procedure for the physical modification of silica gel (SG) for solid-phase extraction and preconcentration of Ni(II) ion. Optimization experiments were carried out at 301 ± 1 K by batch technique. The EDDBP-modified SG was characterized using X-ray Diffraction Spectroscopy (XRD) and Brunaeur-Emmett-Teller (BET) determinations. The adsorption isotherm and kinetic models indicated a physisorption process. The modified SG showed moderate to high adsorption capacity values for Ni(II) ion (~98% removal efficiency) at pH 8. A sorption mechanism for Ni(II) chelation with EDDBP-modified-SG was proposed. These results suggest the procedure has advantages. 相似文献
87.
Chiamaka Obianyor Gary Newnam Bryce E. Clifton Prof. Martha A. Grover Prof. Nicholas V. Hud 《Chembiochem : a European journal of chemical biology》2020,21(23):3359-3370
Chemical ligation is an important tool for the generation of synthetic DNA structures, which are used for a wide range of applications. Surprisingly, reported chemical ligation yields can range from 30 to 95 % for the same chemical activating agent and comparable DNA structures. We report a systematic study of DNA ligation by using a well-defined bimolecular test system and a water-soluble carbodiimide (EDC) as a phosphate-activating agent. Our results emphasize the interplay between template-substrate complex stability and the rates of the chemical steps of ligation, with 3′ phosphate substrates providing yields near 100 % after 24 hours for particularly favorable reaction conditions. Ligation rates are also shown to be sensitive to the identity of the base pairs flanking a nick site, with as much as threefold variation. Finally, the observation that DNA substrates are modified by EDC at rates that can be comparable with ligation rates emphasizes the importance of considering side reactions when designing protocols to maximize ligation yields. 相似文献
88.
为有效提高功能性茶浓缩反渗透膜的回收效率和抗污性能,探究了3种介孔分子硅材料(MCM-41、SBA-15和MCFs)对浓缩膜面聚酰胺层聚合形成过程的结构影响。结果表明,添加质量分数0.02%经磺化预处理的MCM-41于间苯二胺水相可接枝酰氯基团,形成的聚酰胺结构层峰谷粗糙跨度仅为220 nm且交联紧致,膜抗拉伸强度增加37.8%;SBA-15和MCFs相膜面峰谷跨度达500~780 nm,横向褶皱和团聚,结构存在孔道塌陷;改性膜在3 h内对茶多酚、茶多糖、茶蛋白即可达到最大浓缩度,减少50%浓缩时间;MCM-41和SBA-15膜长时间运行的浓缩降率仅为2.8%~6.1%,48 h下降率比显示改性膜达标使用时长增加112.5%~137.5%,亲水性和抗污堵能力均大幅提升,可有效满足功能化茶浓缩精度。 相似文献
89.
We propose a new method of inspecting a surface for fine defects that combines the optical inspection method with observation of the physical behavior of a liquid. A liquid thin film on a substrate behaves as a near-field physical probe that autonomously captures nano-particulate defects. Optical observation of the interfacial behavior of the liquid thin film is used to detect minute defects. This method combines the characteristics of optical detection (i.e., detection from a remote field and simultaneous detectability on a plane) and the high sensitivity of a physical near-field probe. We examined the basic principles of the proposed method through numerical calculation and applied it in experiments to detect fine particulate defects on a silicon substrate for semiconductor manufacturing to demonstrate the validity of the basic concept of the proposed method. 相似文献
90.
Surface-activated bonding (SAB), also called room-temperature bonding, is used in three-dimensional integration technology for semiconductor devices. An Ar fast atom beam (FAB) is used for SAB. However, conventional FAB guns must be replaced after hundreds of minutes of irradiation because carbon abrasion powders are generated by Ar ions sputtering in the gun. Therefore, this study develops a novel FAB gun with improved lifetime. The proposed FAB gun applies magnetic fields to guide Ar ions to reduce sputtering in the gun and improve irradiation efficiency. The proposed FAB gun indicates the possibility of improving gun lifetime. 相似文献